• 姓       名:安德烈
  • 职       称:教授
  • 学       位:博士
  • 所在机构:湖南大学 化学化工学院
  • 出生年月:
  • 籍       贯:
  • 研究方向:有机合成;合成方法学
个人简介 学术成果 发表论文

教育背景

1978.03~1981.12 湖南大学化工系(工学学士)

1984.09~1987.05 湖南大学化工系(工学硕士)

1991.10~1995.03 日本东北大学(Touhoku University)(理学博士)

工作经历

1995.04~1996.03 日本相模中央化学研究所(Sagami Chemical Research Center)(博士后)

1996.04~1997.03 日本富士胶片公司(Fuji Photo Film Co., Ltd.)(博士研究员)

1999.01~2003.01 日本冈山理科大学(Okayama University)(博士后)

1999.06~ 教授(湖南大学化学化工学院)

2000.06~ 博士生导师(湖南大学化学化工学院)

主持过多项国家自科基金、湖南省自科基金(重点)、湖南省科技计划项目(重点)、教育部博士学科基金和留学回国人员基金等科研项目。在J. Am. Chem. Soc.、Angew. Chem. Int. Ed.、Chem.Communu.、J. Org. Chem.、Chem. Eur. J.、Euro. J. Org. Chem.、Chem. Asian. J.、Asian. J. Org. Chem.、J. Mater. Chem.、Phys. Chem. Chem. Phys.等国际期刊上发表过一系列论文,获得了一批发明专利。

科研项目

国家自然科学基金:

双螺旋单元构筑的形态可调衍生物的合成及光学性质研究(No. 20272012)

多头官能基芳炔硫醚的合成和纳米团簇组装行为研究(No. 20672033)

基于刚性芳炔硫醚模板的纳米团簇尺度和形态控制(No. 21072052)

湖南省自然科学基金(重点):基于纳米自组装原理的新功能分子的设计、合成及性能研究(No. 07JJ3026)

湖南省科技计划项目(重点):基于刚性硫醚模板的纳米团簇尺度和形态控制(No. 2011WK4007)

论文专著

1. J. Xiao, Q. Su, W. Dong*, Z.-H. Peng*, Y.-J. Zhang, D.-L. An*, “Copper-Catalyzed Oxidative Alkylation (Methylation) of Phosphonamides and Phosphinamides Using Dicumyl Peroxide”, J. Org. Chem., 2017, 82(18), 9497–9504.

2. Y.-J. Jiang, Y.-P. You, W. Dong*, Z.-H. Peng, Y.-J. Zhang*, D.-L. An*, “Copper-Promoted Desulfitative N-Arylation of Sulfonamides and Sulfoximines with Sodium Arylsulfinates”, J. Org. Chem., 2017, 82(11), 5810–5818.

3. L.-J. Song, J. Xiao, W. Dong*, Z.-H. Peng*, D.-L. An*, “RhIII-Catalyzed Regioselective Preparation of 3-Hetero-Substituted Isocoumarins from Aryl Carboxylic Acids and Alkynes”, Eur. J. Org. Chem., 2017, 341–349.

4. L.-J. Zhong, Q. Su, J. Xiao, Z.-H. Peng, W. Dong*, Y.-J. Zhang*, D.-L. An*, “Ligand-Free Copper-Catalyzed Arylation of Phosphonamides and Phosphinamides with Aryl Siloxanes”, Asian. J. Org. Chem., 2017, 6(8), 1072–1079.

5. P. Huang, Q. Su, W. Dong*, Y.-J Zhang, D.-L. An*, “BrØnsted/Lewis Acids-Promoted Selective Preparations of 3-Hetero Quinolines or 4/5-Hetero Triazoles from Azides and Hetero-Alkynes”, Tetrahedron., 2017, 73(30), 4275–4284.

6. Y.-Q. Xu, Q. Su, W. Dong*, Z.-H. Peng*, D.-L. An*, “The Chan-Evans-Lam N-Arylation of Phosphonic/Phosphinic Amides”, Tetrahedron., 2017, 73(31), 4602–4609.

7. F. Shu, Q.-J. Zheng, W. Dong*, Z.-H. Peng, D.-L. An*, “One-Pot Synthesis of Propynoates and Propynenitriles”, Can. J. Chem., 2017, 95(2), 144–148.

8. H. Chen, Q.-J. Zheng, W. Dong*, Z.-H. Peng*, D.-L. An*, “Preparations of N- and P-Substituted Acetylenes under Metal-Free Conditions”,Synth. Commun., 2016, 46(17), 1438–1445.

9. Z.-J. Zhao, Z.-H. Min, W. Dong*, Z.-H. Peng, D.-L. An*, “Photoredox Catalyst-Mediated Direct Regioselective Phosphonylation of Indoles”, Synth. Commun., 2016, 46(2), 128–133.

10. Y. Zou, J. Xiao, Z.-H. Peng, W. Dong*, D.-L. An*, “Transition Metal-Free Aroylation of NH-Sulfoximines with Methyl Arenes”, Chem. Commun., 2015, (51), 14889–14892.

11. Y. Zhang, Y.-Q. Zhang, J. Xiao, Z.-H. Peng, W. Dong*, D.-L. An*, “Base-Induced One-Pot Preparation of N- or P-Substituted Alkynes”, Eur. J. Org. Chem., 2015, 7806–7815.

12. Y. Zou, Z.-H. Peng, W. Dong*, D.-L. An*, “CuI-Mediated α-Ketoacylation of Sulfoximines under Solvent-Free Conditions”, Eur. J. Org. Chem., 2015, 4913–4921.

13. Z.-J. Zhao, J. Xiao, J.-C. Wang, W. Dong, Z.-H Peng, D.-L. An*, “Anti-inflammatory Effects of Novel Sinomenine Derivatives”, Int. Immunopharmacol., 2015, (29), 354–360.

14. Y.-X. Zhu, Z.-J. Zhao, Y. Zhang, Q. Su, Z.-H. Peng*, D.-L. An*, “Synthesis of Bis(arylethynyl) Selenides by One-Pot Protocol”, Heteroatom Chem., 2015, 26(1), 35–41.

15. Y.-Q Zhang, J. Xiao, W. Dong, Z.-H. Peng, D.-L. An*, “Transition Metal-Free One-Pot Protocol Toward Conjugated Arylbutadiynyl Sulfides”, Heteroatom Chem., 2015, 26(6), 449–454.

16. L. Shi, H.-Y. Feng, P.-J. Zhang, L.-P. Zhou, D.-X. Xie, D.-L. An*, Q.-Y. Cai*, “Synthesis of Haptens and Development of Indirect Enzyme-linked Immunosorbent Assay for Tris(2,3-dibromopropyl) Isocyanurate”, Anal. Biochem: Methods in the Biological Sciences. 2014, 447, 15–22.

17. Q. Su, Z.-J. Zhao, F. Xu, P.-C. Lou, K. Zhang, D.-X. Xie, L. Shi, Q.-Y. Cai*, Z.-H. Peng, D.-L. An*, “One-Pot Preparation of Arylethynyl Sulfides and Bis(arylethynyl) Sulfides”, Eur. J. Org. Chem., 2013, 1551–1557.

18. D.-X. Xie, Z.-J. Ran, Z. Jin, X.-B. Zhang*, D.-L. An*, “A Simple Fluorescent Probe for Zn(II) Based on the Aggregation-Induced Emission”, Dyes Pigments, 2013, 96, 495–499.

19. Q. Su, H. Yan, S.-C. Gao, D.-X. Xie, H. Diao, J.-K. Song, Q.-Y. Cai, G. Shao, Z.-H. Peng, D.-L. An*, “Efficient One-Pot Preparation of Methylthio Arylbutadiynes by Double Elimination Protocol”, Synth. Commun., 2013, 43(19), 2648–2655.

20. L. Shi, L. Zhou, G.-K. Dai, N. Wang, D.-L. An*, Q.-Y. Cai*, “Synthesis of Haptens and Selective Enzyme-linked Immunosorbent Assay of Octachlorostyrene”, Talanta. 2013, 115, 386–393.

21. H. Yan, S. I. Lim, L.-C. Zhang, S.-C. Gao, D. Mott, Y. Le, R. Loukrakpam, D.-L. An*, C.-J. Zhong*, “Rigid, Conjugated and Shaped Arylethynes as Mediators for the Assembly of Gold Nanoparticles”, J. Mater. Chem., 2011, 21, 1890–1901.

22. H. Yan, J. Luo, H.-M. Xie, D.-X. Xie, Q. Su, J. Yin, B. N. Wanjala, H. Diao, D.-L. An*, C.-J. Zhong*, “Cationic Recognition by tert-Butylcalix[4]arene-Functionalized Nanoprobes”, Phys. Chem. Chem. Phys., 2011, 13, 5824–5830.

23. J.-K. Fang, D.-L. An*, K. Wakamatsu, T. Ishikawa, T. Iwanaga, S. Toyota, D. Matsuo, A. Orita*, J. Otera*, “Synthesis and Spectroscopic Study of Diphenylamino-Substituted Phenylene-(poly)ethynylenes: Remarkable Effect of Acetylenic Conjugation Modes”, Tetrahedron Lett., 2010, 51(6), 917–920.

24. J.-K. Fang, D.-L. An*, K. Wakamatsu, T. Ishikawa, T. Iwanaga, S. Toyota, S. Akita, D. Matsuo, A. Orita*, J. Otera*, “Synthesis and Spectroscopic Study of Phenylene-(poly)ethynylenes Substitutede by Amino or Amino/Cyano Groups at Terminal(s): Electronic Effect of Cyano Group on Charge-Transfer Excitation of Acetylenic p-Systems”, Tetrahedron., 2010, 66, 5479–5485.

25. H. Yan, S. I. Lim, Y.-J. Zhang, Q. Chen, D. Mott, W. Wu, D.-L. An*, S. Zhou, C.-J. Zhong*, “Molecularly-Mediated Assembly of Gold Nanoparticles with Interparticle Rigid, Conjugated and Shaped Aryl Ethynyl Structures”, Chem. Commun., 2010, (46), 2218–2220.

26. D.-L. An*, Q. Chen, J.-K. Fang, H. Yan, A. Orita, N. Miura, A. Nakahashi, K. Monde, J. Otera*, “Vibrational CD Spectroscopy as a Powerful Tool for Stereochemical Study of Cyclophynes in Solution”, Tetrahedron Lett., 2009, 50(15), 1689–1692.

27. R.-H. Qiu, X.-H. Xu*, Y.-H. Li, G.-P. Zhang, L.-L. Shao, D.-L. An*, S.-F. Yin*, “Synthesis and Structure of Air-Stable Lewis Acidic Binuclear Complex of Zirconocene Pentafluorophenylsulfonate and its Catalytic Application in the Allylation of Carbonyl Compounds with Tetraallyltin”, Chem. Commun., 2009, (48), 1679–1681.

28. R.-H. Qiu, G.-P Zhang, Y.-Y Zhu, X.-H. Xu*, L.-L. Shao, Y.-H. Li, D.-L. An*, S.-F. Yin*, “Synthesis and Structure of an Extremely Air-Stable Binuclear Hafnocene Perfluorooctanesulfonate Complex and Its Use in Lewis Acid-Catalyzed Reactions”, Chem. Eur. J., 2009, 15(26), 6488–6494.

29. R.-H. Qiu, G.-P. Zhang, X.-H. Xu*, K.-B. Zou, L.-L. Shao, D.-W. Fang, Y.-H. Li, A. Orita*, R. Saijo, H. Mineyama, T. Suenobu, S. Fukuzumi, D.-L. An*, J. Otera*, “Metallocene Bis(perfluoroalkanesulfonate)s as Air-Stable Cationic Lewis Acids”, J. Organomet. Chem., 2009, 694(9-10), 1524–1528.

30. D.-L. An*, Q. Chen, Z.-Y. Zhang, H. Yan, J.-K. Fang, Q. Su, W.-R. Dong, A. Orita*, J. Otera, “Selective Sequential Inter/Intramolecular Eglington Coupling for Chiral Cyclophyne Synthesis”, Synth. Commun., 2009, 39(17), 3092–3100.

31. I-I. S. Lim, C. Vaiana, Z.-Y. Zhang, Y.-J. Zhang, D.-L. An*, C.-J. Zhong*, “X-Shaped Rigid Arylethynes to Mediate the Assembly of Nanoparticles”, J. Am. Chem. Soc., 2007, 129(17), 5368–5369.

32. D.-L. An*, Y.-J. Zhang, Q. Chen, W.-Y. Zhao, H. Yan, A. Orita, J. Otera*, “Enantiopure Double-Helical Phenylene Ethynylene Cyclophynes with the 2,2'-Binaphthyl Template”, Chem. Asian. J., 2007, 2(10), 1299–1304.

33. D.-L. An*, Z.-Y. Zhang, A. Orita, H. Mineyama, J. Otera*, “Convenient Synthesis of (1-Propynyl)arenes through a One-Pot Double Elimination Reaction, and Their Conversion to Enynes”, Synlett., 2007, (12), 1909–1912.

34. D.-L. An*, Z.-H. Peng, A. Orita, A. Kurita, S. Man-e, K. Ohkubo, X.-S. Li, S. Fukuzumi*, J. Otera*, “Organotin Perfluorooctanesulfonates as Air-Stable Lewis Acid Catalysts: Synthesis, Characterization, and Catalysis”, Chem. Eur. J., 2006, 12(6), 1642–1647.

35. Z.-H. Peng, A. Orita, D.-L. An*, J. Otera*, “Fluorous Distannoxane-Catalyzed Acetylation of Alcohols in Heterogeneous Single Fluorous Solvent System”, Tetrahedron Lett., 2005, 46(18), 3187–3189.

36. A. Orita, T. Nakano, D.-L. An, K. Tanikawa, K. Wakamatsu, and J. Otera*, “Metal-Assisted Assembly of Pyridine-Containing Arylene Ethynylene Strands to Enantiopure Double Helicates”, J. Am. Chem. Soc., 2004, 126(33), 10389–10396.

37. D.-L. An, T. Nakano, A. Orita, J. Otera*, “Enantiopure Double-Helical Alkynyl Cyclophanes”, Angew. Chem. Int. Ed. Engl., 2002, 41(1), 171–173.

38. A. Orita, D.-L. An, T. Nakano, J. Otera*, “Sulfoximine Version of Double Elimination Protocol for Synthesis of Chiral Acetylenic Cyclophanes”, Chem. Eur. J., 2002, 8(9), 2005–2010.

39. M. Yoshifuji*, N. Higeta, D.-L. An, K. Toyota, “1,2,3,5,7-Pentaselena-4,6,8-triphosphocane as the Revised Structure for “3,4,5-Triselenoxo-1,2-diselena- 3,4,5-triphospholane” Determined by X-Ray Analysis”, Chem. Lett., 1998, 17–18.

40. D.-L. An, K. Toyota, M. Yasunami, M. Yoshifuji*, “Reactions of (THF)W(CO)5 with Some Diphosphenes Carrying Bulky Aryl and Phenoxy Groups”, J. Organomet. Chem., 1996, 508, 7–12.

41. D.-L. An, K. Toyota, M. Yasunami, M. Yoshifuji*, “3,4,5-Tris(2,4-di-t-butyl-6-methoxyphenyl)-3,4,5-triselenoxo-1,2-diselena-3,4,5-triphospholane as a Selenation Reagent”, Chem. Lett., 1995, 199–200.

42. D.-L. An, K. Toyota, M. Yasunami, M. Yoshifuji*, “Synthesis and Reactions of Diphosphenes Carrying Bulky Aryl and Phenoxy Groups,” Heteroatom Chem., 1995, 6(1), 33–40.

43. M. Yoshifuji*, D.-L. An, K. Toyota, M. Yasunami, “2,4-Di-t-butyl-6-methoxy phenyl Dithioxophosphoranc as a Probe for the Mechanistic Studies of Lawesson’s Reagent”, Tetrahedron Lett., 1994, 35(25), 4379–4382.

44. M. Yoshifuji*, D.-L. An, K. Toyota, M. Yasunami, “Preparations and Sulfurization Reactions of (2,4-Di-t-butyl-6-methoxyphenly)phosphine and 1-(2,4-Di-t-butyl-6-methoxyphenyl)-2-(2,4,6-tri-t-butylphenyl)diphosphene”, Chem. Lett., 1993, 2069–2072.

专利成果

1. 安德烈,苏琼,杨盛,查长军,谢德逊,石磊,蔡青云,芳二炔硫醚的一锅合成方法,ZL 201210055559.5.

2. 安德烈,石磊,蔡青云,周丽萍,戴光坤,苏琼,谢德逊,八氯苯乙烯半抗原、人工抗原和特异性抗体,ZL 201210128680.6.

3. 安德烈,苏琼,梅洪峰,刘元甫,谢德逊,石磊,蔡青云,共轭烯炔硫醚的一锅合成方法,ZL 201210054974.9.

4. 安德烈,石磊,蔡青云,周丽萍,张平静,潘成军,苏琼,谢德逊,三(2,3-二溴丙基)异氰脲酸酯半抗原、人工抗原和抗体及合成,ZL 201210338950.6.

5. 安德烈,石磊,周丽萍,蔡青云,李大庆,苏琼,谢德逊,五溴联苯醚-121的半抗原、人工抗原及抗体,ZL 201310133854.2.

6. 安德烈,刘淑琴,石磊,冯伶俐,彭志鸿,一种铜(II)复合氯化剂及基于铜(II)复合氯化剂合成1-氯-2-芳基乙炔的方法,ZL 201310494743.4.

奖励/荣誉

湖南省自然科学一等奖(2015年)

湖南省高等教育教学成果奖一等奖(2010年)